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Water magnetic leisure dispersion in Organic units: the contribution of proton exchange and implications for your noninvasive detection of cartilage degradation PNAS Oct 23, 2001 Magnetic relaxation continues to be made use of thoroughly to study and characterize biological tissues. Particularly, spin-lattice peace during the rotating frame (T1ρ) of h2o in protein solutions has been shown to generally be sensitive to macromolecular excess weight and composition. Nonetheless, the nature in the contribution from reduced frequency procedures to h2o relaxation continues to be unclear. Now we have examined this problem by researching the h2o T1ρ dispersion in peptide methods (14N- and 15N-labeled)… Exhibit more Magnetic rest has been employed extensively to check and characterize biological tissues. In particular, spin-lattice peace within the rotating frame (T1ρ) of water in protein methods has long been shown to be delicate to macromolecular fat and composition.
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Outcomes attained outline a cytochrome c intermediate observed only poorly prior to and area it early on the most important unfolding pathway. Four distinctive unfolding measures are found to become kinetically purchased in exactly the same pathway sequence inferred just before.
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